AQA GCSE Chemistry

Rates of reaction and energy changes — AQA GCSE Chemistry revision

Free revision notes, key terms, common exam traps and 5 practice questions with answers. About 4 minutes to read.

What speeds a reaction up

  • Higher temperature: particles move faster and collide more often with more energy.
  • Higher concentration or pressure: more particles in the same space, so more frequent collisions.
  • Smaller pieces (bigger surface area): more particles exposed to collide.
  • Catalyst: gives a different pathway with lower activation energy and is not used up.

Energy changes

  • Exothermic reactions release energy and heat the surroundings (combustion, neutralisation).
  • Endothermic reactions take energy in and cool the surroundings (thermal decomposition).
  • Energy change = energy to break bonds − energy released making bonds. Negative = exothermic.

Key terms

Activation energy
The minimum energy particles need to react on collision.
Catalyst
Speeds up a reaction without being used up.
Exothermic
Releases energy to the surroundings — temperature rises.
Collision theory
The idea that reactions only happen when particles collide with enough energy and the correct orientation.
Exothermic reaction
A reaction that transfers energy to the surroundings, so temperature increases.
Endothermic reaction
A reaction that takes in energy from the surroundings, so temperature decreases.

Common exam traps

  • Saying a catalyst lowers the temperature — it lowers activation energy.
  • Saying particles 'collide harder' without mentioning frequency of collisions.
  • Mixing bond breaking (endothermic) with bond making (exothermic).

Practice questions with answers

  1. 1. Which change always increases the rate of reaction?

    • • Cooling the mixture
    • • Using larger lumps
    • • Increasing concentration
    • • Adding water

    Answer: Increasing concentration

    More particles per volume means more frequent successful collisions.

  2. 2. Define activation energy.

    Answer: The minimum energy particles must have for a collision to result in a reaction.

    Say 'minimum energy' for the mark.

  3. 3. Bond breaking is:

    • • Exothermic
    • • Endothermic
    • • Neither
    • • Both

    Answer: Endothermic

    Energy must be supplied to break bonds.

  4. 4. A reaction's temperature drops. What type of reaction is it?

    Answer: Endothermic — energy is taken in from the surroundings.

    Surroundings cool because energy moves into the reaction.

  5. 5. Which factor does NOT usually increase the rate of a reaction?

    • • Decreasing temperature
    • • Increasing concentration
    • • Adding a catalyst
    • • Increasing surface area

    Answer: Decreasing temperature

    Lower temperature means less kinetic energy and fewer successful collisions, slowing the reaction.

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